Extractive spectrophotometric determination of Co(II) using 5-Chlorosalicylaldehyde thiosemicarbazone


EOI: 10.11242/viva-tech.01.05.001

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Citation

Priyanka Rodrigues, Sunetra Chaudhary, "Extractive spectrophotometric determination of Co(II) using 5-Chlorosalicylaldehyde thiosemicarbazone ", VIVA-IJRI Volume 1, Issue 7, Article 1, pp. 1-6, 2024. Published by Humanities and Applied Sciences, VIVA Institute of Technology, Virar, India.

Abstract

The complex of 5-Chlorosalicylaldehyde thiosemicarbazone (CSTSC) and Co(II) has been quantitatively extracted in butyl acetate in the pH range of 4.6–5.2 after equilibrating for 60 sec. Up to 6.0 μg mL-1 concentration of Co(II), the complex of 5-Chlorosalicylaldehyde thiosemicarbazone with Co(II) in butyl acetate follows Beer’s law, with its maximum absorbance occurring at 425 nm. By employing the Jobs continuous variation method, the composition 1:2 has been determined for the Co(II)-CSTSC complex. The extracted complex remained stable for more than 24 hours. 6.637 X 10-3 μg cm-2 was determined to be Sandell's sensitivity, whereas 0.887 X 104 L mol-1 cm-1 was the molar absorptivity. Synthetic samples have been effectively analysed using this method.

Keywords

Butyl acetate, extraction, Cobalt, CSTSC, Spectrophotometry.

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